Making soluble salts from insoluble substances
A solubleAble to dissolve in solvent. For example, sugar is soluble in water because it dissolves to form sugar solution. saltThe substance formed when the hydrogen ion in an acid is replaced by a metal ion. can be prepared by reacting an acidSubstance producing more hydrogen ions than hydroxide ions when dissolved in water. with a suitable insolubleUnable to dissolve in a particular solvent. For example, sand is insoluble in water. reactantA substance that reacts together with another substance to form products during a chemical reaction. including:
- a metal
- a metal oxide
- a metal hydroxide
- a carbonate
The insoluble reactant chosen depends upon the particular salt required.
For example, copper does not react with dilute acids, so this metal cannot be used. On the other hand, sodium is too reactive to be used safely.
As the reaction between metals and acids produces flammableAble to ignite and burn. hydrogen, chemists usually make salts by reacting a metal oxide or a metal carbonate with an acid.
Choosing reactants
The table shows some examples of the salts produced by different combinations of insoluble reactants and acids.
Hydrochloric acid | Sulfuric acid | Nitric acid | |
Copper oxide | Copper chloride | Copper sulfate | Copper nitrate |
Aluminium hydroxide | Aluminium chloride | Aluminium sulfate | Aluminium nitrate |
Zinc carbonate | Zinc chloride | Zinc sulfate | Zinc nitrate |
Copper oxide | |
---|---|
Hydrochloric acid | Copper chloride |
Sulfuric acid | Copper sulfate |
Nitric acid | Copper nitrate |
Aluminium hydroxide | |
---|---|
Hydrochloric acid | Aluminium chloride |
Sulfuric acid | Aluminium sulfate |
Nitric acid | Aluminium nitrate |
Zinc carbonate | |
---|---|
Hydrochloric acid | Zinc chloride |
Sulfuric acid | Zinc sulfate |
Nitric acid | Zinc nitrate |
Making a salt
To make a soluble salt from an acid and an insoluble reactant:
- Add powdered insoluble reactant to acid in a beaker, one spatula at a time, stirring to mix. Continue adding powder until it is in excessIn chemistry, a substance is in excess if there is more than enough of it to react with another reactant. (some unreacted powder is left over). All the acid has now reacted.
- Filter the mixture in the beaker to remove the excess solid. The filtrate now contains only the salt and water.
- Heat the solution in an evaporating dish over a water bath. Stop heating when small crystals start to appear around the edge of the evaporating basin. The solution is now saturatedUnable to contain any more liquid..
- Leave the saturated solution at room temperature for a day or two. This gives time for large crystalA solid containing particles (atoms, molecules or ions) joined together to form a regular arrangement or repeating pattern. to form.
- If necessary, dry the crystals by dabbing gently with filter paper.
Question
Give the names of two substances that react to make zinc sulfate.
Select two from the following:
- sulfuric acid and zinc
- zinc oxide
- zinc oxide
- zinc hydroxide