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Writing formulae of ionic compounds

The of an shows the relative numbers of the it contains. For example:

  • the formula for sodium chloride is NaCl - it shows that for every Na+ ion there is one Cl- ion
  • the formula for magnesium chloride is MgCl2 - it shows that for every Mg2+ ion there are two Cl- ions

Working out an ionic formula

The formula for an ionic compound must contain the same number of positive and negative . This is so that the charges are balanced and the compound is neutral overall. Here are some examples.

Example 1

Sodium chloride contains Na+ and Cl- ions:

  • this is one positive charge and one negative charge
  • the charges are balanced (add up to zero)
  • so the formula is NaCl

Example 2

Magnesium oxide contains Mg2+ and O2- ions:

  • this is two positive charges and two negative charges
  • the charges are balanced
  • so the formula is MgO

Example 3

Aluminium oxide contains Al3+ and O2- ions:

  • this is three positive charges and two negative charges
  • to balance we need, two Al3+ ions and three O2- ions
  • so the formula is Al2O3