Carboxylic acids
The carboxylic acidA homologous series of compounds that contain the carboxyl functional group, -COOH. form a homologous seriesA 'family' of organic compounds that have the same functional group and similar chemical properties. . Like all homologous series, the carboxylic acids:
- have the same general formulaAn algebraic formula that sets out a rule or trend which is followed by all members of a homologous series. For example, all non-cyclic alkanes have the general formula CnH2n+2.
- differ by CH2 in molecular formulaChemical formula showing the actual number of atoms of each element in a molecule. from neighbouring compoundA substance formed by the chemical union of two or more elements.
- show a gradual variation in physical propertiesA description of the appearance of a substance or how it acts without involving chemical reactions. For example, state, melting point, conductivity, etc., such as their boiling pointThe temperature at which a substance rapidly changes from a liquid to a gas.
- have similar chemical propertiesA description of how a substance reacts with other substances. For example, flammability, pH, reaction with acid, etc.
Functional group
The functional groupAn atom, or group of atoms, that determines the main chemical properties of an organic compound. in the carboxylic acids is the carboxylA functional group found in the carboxylic acids, -COOH. group, 鈥揅OOH. It is responsible for the typical reactions of carboxylic acids, which are weak acidSubstance producing more hydrogen ions than hydroxide ions when dissolved in water. . Vinegar is a dilute solution of ethanoic acid.
Structures
The table shows four carboxylic acids, their formulae and their structures.
Acid properties
The carboxylic acids have the typical properties of acids. For example, they:
- dissolveWhen a substance breaks up and mixes completely with a solvent to produce a solution. in water to form acidicHaving a pH lower than 7.solutionMixture formed by a solute and a solvent. with pHScale of acidity or alkalinity. A pH (power of hydrogen) value below 7 is acidic, a pH value above 7 is alkaline. values less than 7
- react with metalShiny element that is a good conductor of electricity and heat, and which forms basic oxides. to form a saltA compound formed by neutralisation of an acid by a base, eg a metal oxide, as the result of hydrogen ions in the acid being replaced by metal ions or other positive ions. Sodium chloride, common salt, is one such compound. and hydrogen
- react with baseA substance that reacts with an acid to neutralise it and produce a salt. to form a salt and water
- react with carbonates to form a salt, water and carbon dioxide
These properties are due to the 鈥揅OOH functional group.