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Properties of ionic compounds

have regular structures, called giant . In a giant ionic lattice, there are strong electrostatic forces of attraction acting in all directions between the oppositely charged ions. The structure and bonding of ionic compounds explain their .

Learn more on properties of ionic compounds in this podcast.

High melting points and boiling points

Energy must be transferred to a substance to make it melt or boil. This energy overcomes the strong electrostatic forces of attraction which act in all directions between the oppositely charged ions:

  • some forces are overcome during melting
  • all remaining forces are overcome during boiling

The more energy needed, the higher the or . Since the electrostatic forces of attraction between oppositely charged ions are strong, their melting and boiling points are high.

CompoundMelting pointBoiling point
NaCl801掳颁1413掳颁
MgO2852掳颁3600掳颁
CompoundNaCl
Melting point801掳颁
Boiling point1413掳颁
CompoundMgO
Melting point2852掳颁
Boiling point3600掳颁

You can see from the data in the table that sodium chloride is a solid below 801掳颁, a liquid between 801掳颁 and 1413掳颁, and a gas at temperatures higher than 1413掳颁.

Conducting electricity

A substance can electricity if:

  • it contains , such as ions, and
  • these particles are free to move from place to place

An ionic compound can conduct electricity when:

  • it has to form a liquid, or
  • it has dissolved in water to form an solution

Both these processes allow ions to move from place to place. Ionic compounds cannot conduct electricity in the solid state because their ions are held in fixed positions and cannot move.