Pure substances
The meaning of pure
The word pureA substance that consists of only one element or only one compound. is used in chemistry in a different way from its everyday meaning. For example, shops sell cartons labelled as 'pure' orange juice. The label means that the contents are just orange juice, with no other substances added. However, the juice is not pure in the chemical sense, because it contains different substances mixed together. In chemistry:
- a pure substance consists only of one elementA substance made of one type of atom only. or one compoundA substance formed by the chemical union of two or more elements.
- a mixtureTwo or more substances that are not joined together. The substances can be elements, compounds, or both. consists of two or more different substances, not chemically joined together
Different types of chemical substance
- an element contains just one type of atomThe smallest part of an element that can exist.
- a compound contains two or more types of atom joined together
- a mixture contains two or more different substances that are not joined together
- the different substances in a mixture can be elements or compounds
The table shows some examples:
Distinguishing between pure substances and mixtures
Pure substances have a sharp melting pointThe temperature at which a solid changes into a liquid as it is heated. but mixtures meltingThe process that occurs when a solid turns into a liquid when it is heated. over a range of temperatures. This difference is most easily seen when the temperature of a liquid is measured as it cools and freezeA change of state in which liquid becomes solid by cooling.. The graph shows the cooling curve for a sample of a compound called salol.
The horizontal part of the graph shows that the salol has a sharp melting point, so it is pure. impureA substance that consists of more than one element or compound. salol (a mixture of salol and other substances) would produce a gradual fall in temperature as it freezes.
Question
A student tests the melting point of a sample of sulfur. It starts melting at 95-101掳C but does not melt completely until the temperature is 113掳C. According to a data book, the melting point of sulfur is 115掳C. Is this sample of sulfur pure or impure?
It is impure, because it melts over a range of temperatures, and the melting point is not the same as the 'standard' reference melting point for sulfur.