Concentration of solutions
A solutionMixture formed by a solute and a solvent. forms when a soluteThe dissolved substance in a solution. dissolveWhen a substance breaks up and mixes completely with a solvent to produce a solution. in a solventThe liquid in which the solute dissolves to form a solution.. The concentrationA measure of the mass or amount of solute dissolved in a given volume of solvent or solution. of a solution is a measure of how 'crowded' the solute particles are. The more concentrated the solution, the more particles it contains in a given volumeThe volume of a three-dimensional shape is a measure of the amount of space or capacity it occupies, eg an average can of fizzy drink has a volume of 330 ml..
Calculating concentration
The concentration of a solution can be calculated using:
- the massThe amount of matter an object contains. Mass is measured in kilograms (kg) or grams (g). of dissolved solute in grams, g
- the volume of solution (or solvent) in cubic decimetres, dm3
The units for concentration can also be shown as g dm-3, but this means the same as g/dm3.
Worked example
8 g of sodium hydroxide is dissolved in 2 dm3 of water. Calculate the concentration of the sodium hydroxide solution formed.
concentration = \(\frac{\textup{mass~of~solute~in~g}}{\textup{volume~in~dm}^3}\)
concentration = \(\frac{\textup{8~g}}{\textup{2~dm}^3}\)
concentration = 4 g/dm3
Volume units
Apparatus used to measure volumes is usually marked in cm3 or ml. Although these are different units, they describe the same volume. For example, 250 ml = 250 cm3.
Volumes used in concentration calculations must be in dm3, not in cm3 or ml. It is useful to know that 1 dm3 = 1000 cm3. This means:
- divide by 1000 to convert from cm3 to dm3
- multiply by 1000 to convert from dm3 to cm3
For example, 250 cm3 is 0.25 dm3 (250 梅 1000). It is often easiest to convert from cm3 to dm3 before continuing with a concentration calculation.
Question
100 cm3 of dilute hydrochloric acid contains 0.5 g of dissolved hydrogen chloride. Calculate the concentration of the acid in g/dm3.
volume of acid = 100 梅 1000 = 0.1 dm3
concentration of acid = \(\frac{\textup{0.5}}{\textup{0.1}}\)
= 5 g/dm3
Calculating the mass of solute
Rearranging the equation for concentration allows the mass of solute to be calculated:
mass of solute in g = concentration in g/dm3 脳 volume in dm3
Worked example
A solution of sodium chloride has a concentration of 10 g/dm3. What mass of sodium chloride is dissolved in 2 dm3 of the solution?
mass of solute in g = concentration in g/dm3 脳 volume in dm3
= 10 g/dm3 脳 2 dm3
= 20 g
Higher tier
The concentration of a solution can be changed:
- concentration can be increased by dissolving more solute in a given volume of solution - this increases the mass of the solute
- concentration can be increased by allowing some of the solvent to evaporate - this decreases the volume of the solution