Rates, concentration and pressure
The greater the frequencyThe total number of times an event occurs. of successful collisionA collision between reactant particles that has enough energy for a reaction to happen., the greater the rate of reaction. If the concentrationThe concentration of a solution tells us how much of a substance is dissolved in water. The higher the concentration, the more particles of the substance are present. of a reacting solutionMixture formed by a solute and a solvent. or the pressureForce exerted over an area. The greater the pressure, the greater the force exerted over the same area. of a reacting gas is increased:
- the reactantA substance that reacts together with another substance to form products during a chemical reaction.particleA general term for a small piece of matter. For example, protons, neutrons, electrons, atoms, ions or molecules. are closer together
- the frequency of collisions between reactant particles increases
- therefore the rate of reaction increases
Note that the mean energyThe capacity of a system to do work or the quantity required for mechanical work to take place. Measured in joules (J). For example, a man transfers 100 J of energy when moving a wheelbarrow. of the particles does not change. However, since the frequency of collisions increases (they happen more often) the frequency of successful collisions also increases.
Graphs
The rates of two or more reactions can be compared using a graph of massThe amount of matter an object contains. Mass is measured in kilograms (kg) or grams (g). or volumeThe volume of a three-dimensional shape is a measure of the amount of space or capacity it occupies, eg an average can of fizzy drink has a volume of 330 ml. of productA substance formed in a chemical reaction. formed against time. The graph shows this for two reactions.
The gradientAnother word for steepness. On a graph, the gradient is defined as being the change in the 'y' value divided by the change in the 'x' value. It defines how steep a line is. of the line is equal to the rate of reaction. The faster reaction at the higher concentration or pressure:
- gives a steeper line
- finishes sooner