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Covalent bonding - AQA SynergyGiant covalent structures

A covalent bond is a shared pair of electrons. Covalent bonding results in the formation of molecules or giant structures. Substances with small molecules have low melting and boiling points and do not conduct electricity. Giant covalent substances have very high melting points.

Part of Combined ScienceInteractions over small and large distances

Giant covalent structures

A small number of covalent substances form giant structures instead of small molecules. In these structures, the are bonded to each other with .

Learn more on properties of giant covalent compounds in this podcast.

Examples

Silicon dioxide, also called silica, is the main found in sand. It is an example of a substance with a . It contains many silicon and oxygen atoms.

All the atoms in its structure are linked to each other by strong covalent bonds. The atoms are joined to each other in a regular arrangement, forming a giant covalent structure. There is no set number of atoms joined together in this type of structure.

Diamond is another example of a giant covalent structure. Diamond is made up of carbon atoms - it is a form of carbon.

Covalent structure of silica
Figure caption,
Silica has a giant covalent structure containing silicon atoms (grey) and oxygen atoms (red)

High melting points and boiling points

Substances with giant covalent structures are solids at room temperature. They have very high and . This is because large amounts of are needed to overcome their strong covalent bonds to make them melt or boil.

Conduction of electricity

Most substances with giant covalent structures have no charged particles that are free to move. This means that most cannot electricity. Graphite, a form of carbon which can conduct electricity, is an exception.

Question

State three properties that are typical of substances with giant covalent structures.