Forming ions
An ionElectrically charged particle, formed when an atom or molecule gains or loses electrons. is an atomThe smallest part of an element that can exist. or group of atoms with a positive or negative chargeProperty of matter that causes a force when near another charge. Charge comes in two forms, positive and negative. For example, a negative charge causes a repulsive force on a neighbouring negative charge.. Ions form when atoms lose or gain electronSubatomic particle, with a negative charge and a negligible mass relative to protons and neutrons. to obtain a full outer shell:
- metalShiny element that is a good conductor of electricity and heat, and which forms basic oxides. atoms lose electrons to form positively charged ions
- non-metalElement that is a poor conductor of electricity and heat, and which forms acidic oxides. atoms gain electrons to form negatively charged ions
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Forming positive ions
Metal atoms lose electrons from their outer shell when they form ions:
- the ions formed are positive, with more protonSubatomic particle with a positive charge and a relative mass of 1. The relative charge of a proton is +1. than electrons
- the ions formed have full outer shells
For elements in groupA vertical column in the periodic table containing elements with similar chemical properties. 1, 2 and 3, the number of electrons lost is the same as the group number.
Forming negative ions
The outer shell of non-metal atoms gains electrons when they form ions:
- the ions formed are negative, because they have more electrons than protons
- the ions formed have full outer shells
For groups 6 and 7, the number of electrons gained is equal to (8 - group number).
Example of ion charges and groups
Group number | Element | Charge on ions | Symbol of ion |
1 | Na | + | Na+ |
2 | Mg | 2+ | Mg2+ |
3 | Al | 3+ | Al3+ |
6 | O | 2- | O2- |
7 | Cl | - | Cl- |
Group number | 1 |
---|---|
Element | Na |
Charge on ions | + |
Symbol of ion | Na+ |
Group number | 2 |
---|---|
Element | Mg |
Charge on ions | 2+ |
Symbol of ion | Mg2+ |
Group number | 3 |
---|---|
Element | Al |
Charge on ions | 3+ |
Symbol of ion | Al3+ |
Group number | 6 |
---|---|
Element | O |
Charge on ions | 2- |
Symbol of ion | O2- |
Group number | 7 |
---|---|
Element | Cl |
Charge on ions | - |
Symbol of ion | Cl- |
The numbers of protons, neutronUncharged subatomic particle, with a mass of 1 relative to a proton. The relative charge of a neutron is 0. and electrons in an ion can be calculated from its atomic numberThe number of protons in the nucleus of an atom. Also called the proton number., mass numberThe number of protons and neutrons found in the nucleus of an atom. and ionic charge.
Remember that:
- atomic number = protons
- mass number = protons + neutrons
- electrons = protons (if atom is neutral)
- positive ions have lost electrons
- negative ions have gained electrons
Some examples are shown in the table below:
Ion name | Ion symbol | Atomic number | Mass number | Protons | Neutrons | Electrons |
Aluminium | Al3+ | 13 | 27 | 13 | 14 | 10 |
Calcium | Ca2+ | 20 | 40 | 20 | 20 | 18 |
Sulfide | S2- | 16 | 32 | 16 | 16 | 18 |
Ion name | Aluminium |
---|---|
Ion symbol | Al3+ |
Atomic number | 13 |
Mass number | 27 |
Protons | 13 |
Neutrons | 14 |
Electrons | 10 |
Ion name | Calcium |
---|---|
Ion symbol | Ca2+ |
Atomic number | 20 |
Mass number | 40 |
Protons | 20 |
Neutrons | 20 |
Electrons | 18 |
Ion name | Sulfide |
---|---|
Ion symbol | S2- |
Atomic number | 16 |
Mass number | 32 |
Protons | 16 |
Neutrons | 16 |
Electrons | 18 |
More guides on this topic
- Formulae and equations - Edexcel
- Hazards and risks - Edexcel
- Atomic structure - Edexcel
- The periodic table - Edexcel
- Simple molecular substances - Edexcel
- Giant covalent substances - Edexcel
- Metals and non-metals - Edexcel
- Calculations for all students - Edexcel
- Higher tier only calculations - Edexcel
- Sample exam questions - key concepts in chemistry - Edexcel