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Group 7 - physical properties

contains placed in a vertical column on the right of the . The elements in group 7 are called the .

Periodic table with Group 7 in red.
Figure caption,
Group 7 is on the right-hand side of the periodic table, next to group 0

The halogens show trends in their and .

Physical properties

The halogens exist as simple . Each molecule is made up of a pair of halogen joined by a single . In all groups of the periodic table, the further down the group an element is, the higher its .

The table shows the colour and physical of chlorine, bromine and iodine at room temperature.

ElementColourState
Chlorine, Cl2Pale greenGas
Bromine, Br2BrownLiquid
Iodine, I2Purple-blackSolid
ElementChlorine, Cl2
ColourPale green
StateGas
ElementBromine, Br2
ColourBrown
StateLiquid
ElementIodine, I2
ColourPurple-black
StateSolid

In group 7, the further down the group an element is, the higher its and . This is because, going down group 7:

  • the molecules become larger
  • the intermolecular become stronger
  • more is needed to overcome these forces

Question

The graph shows the melting and boiling points of the first four group 7 elements. Astatine is placed below iodine in group 7. Predict the melting and boiling points of astatine, and its state at room temperature.

Bar chart showing how the melting and boiling points of the halogens increase going down group 7

The test for chlorine gas

To test for chlorine, use damp blue litmus paper. The blue colour will turn to red and then to white.

Chlorine gas reacts with water to produce an acidic solution which is also an effective bleach. This explains how the test for chlorine works. The acidic solution formed on the damp litmus paper turns the indicator red. Then the bleach turns the red colour to white.